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Record W2340942477 · doi:10.1021/acssuschemeng.6b00255

Sustainable Composites from Biodegradable Polyester Modified with Camelina Meal: Synergistic Effects of Multicomponents on Ductility Enhancement

2016· article· en· W2340942477 on OpenAlexafffund
Zhaoshu Chen, Ning Lin, Shanjun Gao, Changhua Liu, Jin Huang, Peter R. Chang

Bibliographic record

VenueACS Sustainable Chemistry & Engineering · 2016
Typearticle
Languageen
FieldMaterials Science
Topicbiodegradable polymer synthesis and properties
Canadian institutionsAgriculture and Agri-Food Canada
FundersNatural Resources CanadaMinistry of Education of the People's Republic of ChinaNational Natural Science Foundation of China
KeywordsMaterials scienceComposite materialPlasticizerComposite numberPolyesterCompression moldingFiller (materials)ElongationCamelinaDuctility (Earth science)BiopolymerBiodegradable polymerPolymerUltimate tensile strengthChemistry

Abstract

fetched live from OpenAlex

Biodegradable composites were prepared via a melt compression molding process with dehulled camelina meal (DeCM) as the biomass-based filler and poly(3-hydroxybutyrate- co -4-hydroxybutyrate) (P(3,4)HB) or poly(butylene succinate) (PBS) as the aliphatic polyester matrix. The incorporation of 25 parts DeCM into the composite promoted an impressive increase of 461% in the elongation at break of the P(3,4)HB-based composites. Concurrently, the elongation at break of PBS-based composites containing 20 parts of DeCM increased by 71% over the neat materials. Extraction of components from the DeCM (oil and protein) showed that oil had a critical plasticization effect that enhanced the ductility of the composites. Compared with neat materials, the presence of DeCM filler had no significant effect on the thermal properties of the composites and preserved the original crystalline structure of the polyester component in the composites. Renewable, economical, and biodegradable DeCM is a promising functional biomass-based filler for polyester-based composites, and it is worth noting that the synergistic effects of multicomponents in DeCM played a key role in ductility enhancement.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.001
Threshold uncertainty score0.003

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0010.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0010.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.006
GPT teacher head0.184
Teacher spread0.178 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations16
Published2016
Admission routes2
Has abstractyes

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Same venueACS Sustainable Chemistry & EngineeringSame topicbiodegradable polymer synthesis and propertiesFrench-language works237,207