Preparation of L-Asparagine molecularly imprinted polymer usinionic liuid as cosolvent
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Bibliographic record
Abstract
The molecularly imprinted polymers(L-Asn-MIPs-IL)were firstly prepared by precipitation polymerization using 4-vinylpyridine(4-VP)as functional monomers and ethylene glycol dimethyl acrylate(EGDMA)as cross-linker in the presence of L-Asparagine as template molecule in aqueous-acetonitrile and 1-butyl-3-methylimidazolium bromide[Bmim]Br solution.The scanning electron microscopy(SEM)exhibited that the L-AsnMIPs-IL were small particles with narrow particle size distributions.Compared with that of the molecularly imprinted polymers(L-Asn-MIPs)synthesized in aqueous-acetonitrile solution without[Bmim]Br,the yield and specific surface area of L-Asn-MIPs-IL was significantly higher.The results showed that L-Asn-MIPs-IL for LAsn possessed higher saturation adsorption amount,faster adsorption speed,better selective adsorption capacity and finer separation property for the enantiomers of Asparagine compared to L-Asn-MIPs.The equilibrium adsorption amount in 100mg/L L-Asn solution was 15.49mg/g,the adsorption equilibrium can be reached within 160 min and the separation factor between L-Asn and L-Arg was 1.68.
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Full frame distilled prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.001 | 0.001 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.000 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.004 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it