Synthesis, Characterization and Nonlinear Optical Properties of a Series Charge Transfer Salts Based on H_3PMo_(12-n)W_nO_( 40) ·mH_2O and 2,7-Dimethylquinoline
Bibliographic record
Abstract
A series charge trnasfer salts,[DMQH] 3PMo 12-n W nO 40 (n=0,1,3,9,11,12), were synthesized from H 3PMo 12-n W nO 40 ·mH 2O and 2,7_dimethylquinoline and characterized by elemental analysis, IR spectra and electronic spectra. The results indicate that there is a strong interaction between the cation and the anion in the solid state;the heteropoly blue will be produced after the samples are irradiated under light. The study of second and third order nonlinear optical indicate that the SHG and the third_order susceptibilities of the charge transfer salts are increased the increase of the tungsten number in the molecules.
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How this classification was reachedexpand
Full frame distilled prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.000 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.000 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from itClassification
machine, unvalidatedMachine predicted; a candidate call from one teacher head, not a consensus.
How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".