Self-assembly of Phthalocyanine-carbon Nanotubes Dispersed in Micelle and Light Induced Long-lived Charge Separation State
Bibliographic record
Abstract
To mimic the primary process in photosynthesis,tetrasulfonated zinc phthalocyanine(ZnPcS4) and single-walled carbon nanotubes(SWCNT) were assembled to noncovalent electron donor-acceptor(D-A) complex assisted by sodium dodecyl sulfate(SDS) micelle,which disaggregate both SWCNTs and phthalocyanines in aqueous solution.The D-A complex is featured by the new absorption at 707 nm and completely non fluorescence,due to the efficient intra-molecular photo induced electron transfer revealed by both steady state and time resolved fluorescence spectra.The charge separation state(CSS) was observed by laser flash photolysis and showed a long lifetime of 42 μs observable by kinetic analysis.The long-lived CSS is due to the triplet electron transfer which is made possible by the low oxidation potential of the phthalocyanine(good donor) and the low reduction potential of SWCNT(good acceptor).The result shows that SWCNT may be applied in artificial photosynthesis.
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How this classification was reachedexpand
Full frame distilled prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.001 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.001 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.001 |
| Open science | 0.000 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.000 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from itClassification
machine, unvalidatedMachine predicted; a candidate call from one teacher head, not a consensus.
How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".