Characterization of Pd⋯H–C interactions in bis-dimethyldithiocarbamate palladium(<scp>ii</scp>) and its deuterated analog by luminescence spectroscopy at variable pressure
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Bibliographic record
Abstract
We present the variable-pressure d-d luminescence spectra of crystalline bis-dimethyldithiocarbamate palladium(ii) and its deuterated analog. The energies and shifts of the band maxima provide evidence for intermolecular PdH-C interactions, with quantitative differences observed for the deuterated complex. Shifts show distinct interactions in three pressure ranges between 1 bar and 85 kbar.
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| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.001 |
| Open science | 0.000 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.001 | 0.000 |
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