SYNTHESIS AND CHARACTERIZATION OF DENDRITIC CARBOSILANE BASED MACROPHOTOINITIATOR
Why this work is in the frame
A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.
Bibliographic record
Abstract
A carbosilane dendrimer based macrophotoinitiator(MPI-185) containing benzophenone moiety terminal groups was synthesized by a divergent hydrosilylation/allylation reaction sequence followed by alcoholysis of the silicon chloride end groups.The structure of MPI-185 was characterized by FTIR,()~1H-NMR,()~(13)C-NMR,and()~(29)Si-NMR,and its intrinsic viscosity,molecular weight and polydispersity were meassured on by using a GPC complex system.Its reactivity was tested via curing a sensitive epoxy acrylate(EA) resin using FTIR,and the thermal property of films cured was measured by TGA.The results were compared with those of a small molecule photoinitiator(185).It was found that the curring efficiency of macrophoinitiator(MPI-185) was satisfactory,and the thermal degradation temperature of EA resin cured with MPI-185 was also markedly improved.
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Full frame distilled prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.000 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.001 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it