SYNTHESIS AND CURING BEHAVIORS OF UV CURABLE HYPERBRANCHED POLYSILOXANE
Bibliographic record
Abstract
Two UV curable hyperbranchend polysiloxanes(Ⅰ and Ⅲ) containing vinyl and allyl end groups and an UV cationic curable hyperbranched polymer Ⅱ-Ep with epoxy end groups,were synthesized via the polyhydrosilylation using AB_2 type monomers.All hydrosilylation reactions were catalyzed by(Pt/C) or chloroplatinic acid.Three AB_2 type monomers were synthesized via hydrolyzation of functional chlorosilane prepared by using Grignardeagents,and dichlorosilane.The molecular structures of the polymers were characterized by()~1H-,()~(29)Si-NMR,FTIR and GPC,and the UV-curing behaviors of polymers in different atmospheres and different photoaccelerators were also investigated.
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How this classification was reachedexpand
Full frame machine prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.
Distilled classifier scores by category (both heads)
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.000 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.001 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from itClassification
machine, unvalidatedMachine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.
How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".