Synthesis and Characterization of Three-Dimensionally Ordered Macroporous (3DOM) Titania-Silica Mixed Oxides
Bibliographic record
Abstract
Three-Dimentionally Ordered macroporous titanium-silica mixed oxides were successfully synthesized by using polystyren sphere colloid crystal as the template and the sol of tetraethyl silicate and tetrabutoxy-titane as the filling fluid. The sol filled in the voids among spheres by capillary forces, and then transformed into gel in situ. Latex spheres were removed by calcination(5℃/min; 300℃,5h; 570℃, 5h). The macroporous samples show a beautiful iridescence in reflected light. SEM indicates that the pores are about 500nm in size and arrayed periodically in a face-centered cubic (fcc) structure and connected with each other by small windows. EDS indicates that the Si/Ti molar ratio is 2.7. XRD indicates the wall of the pores is amorphous.
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How this classification was reachedexpand
Full frame distilled prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.001 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.000 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.005 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from itClassification
machine, unvalidatedMachine predicted; a candidate call from one teacher head, not a consensus.
How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".