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Record W2375128803

Synthesis and Crystal Structure of 5-(Benzal(4-methoxyl))imidazoline-2,4-dione under Microwave Irradiation

2003· article· en· W2375128803 on OpenAlexaff
Guo Chenga

Bibliographic record

Venuenot available
Typearticle
Languageen
FieldChemistry
TopicSynthesis and Characterization of Heterocyclic Compounds
Canadian institutionsCAE (Canada)
Fundersnot available
KeywordsChemistryTriclinic crystal systemCrystal structureDihedral angleCrystallographyHydrogen bondHydantoinCrystal (programming language)Microwave irradiationStereochemistryMoleculeOrganic chemistry
DOInot available

Abstract

fetched live from OpenAlex

The title compound (C11H10N2O3) has been synthesized by the reaction of 4-methoxylphenyl aldehyde with hydantoin under microwave irradiation and its structure was determined by single-crystal X-ray diffraction. The crystal is of triclinic, space group P?with a = 5.346(1), b = 10.212(1), c = 10.368(2) , = 72.34(2), = 75.35(2), = 78.09(2), V = 516.6(2) ?, Mr = 218.21, Z = 2, Dc = 1.403 g/cm3, = 0.104 mm-1, F(000) = 228, R = 0.0442 and wR = 0.1152. X-ray analysis reveals that the dihedral angle between planes 1 (C(8), C(9), C(10), N(1) and N(2)) and 2 (C(1)~C(6)) is 5.45, and intermolecular hydrogen bonding as well as network structure is also found in the crystal.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesInsufficient payload (model declined to judge)
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.009
Threshold uncertainty score0.996

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0050.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.011
GPT teacher head0.222
Teacher spread0.211 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations0
Published2003
Admission routes1
Has abstractyes

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