Thermal Decomposition Kinetics of Glycine Complexes with Heavy Rare Earth Bromides
Bibliographic record
Abstract
Thermal decomposition kinetics of three glycine complexes with heavy rare earth bromides were studied under non-isothermal conditions by using DSC techniques. The kinetic parameters (activation energy E,pre-expontial factor A)were obtained from analysis of the DSC cures by the Ozawa method, the Kissinger method、the Achar method and the Coats-Redfern method respectively. The most probable mechanisms function for the fist、the second and the fourth stage were suggested by comparing the kinetic parameters. The kinetic equation may be expressed as dα/dt = A/β·e-E/RT(1-α) ,dα/dt = A/β·e-E/RT(1-α)2 and dα/dt=A/β·e-E/RT(1-α)2.
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How this classification was reachedexpand
Full frame distilled prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.000 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.004 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from itClassification
machine, unvalidatedMachine predicted; a candidate call from one teacher head, not a consensus.
How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".