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Record W2381428192

The Investigation of Thermal Decomposition Kinetics for PNIMMO by TG-MS

2007· article· en· W2381428192 on OpenAlex

Why this work is in the frame

A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.

affAt least one author lists a Canadian institution in the pinned OpenAlex snapshot.

Bibliographic record

VenueInitiators & Pyrotechnics · 2007
Typearticle
Languageen
FieldMaterials Science
TopicThermal and Kinetic Analysis
Canadian institutionsScience North
Fundersnot available
KeywordsThermal decompositionDecompositionKineticsChemistryChemical decompositionPhysical chemistryThermodynamicsMaterials scienceOrganic chemistryPhysics
DOInot available

Abstract

fetched live from OpenAlex

The whole processes of the PNIMMO thermal decomposition was investigated by using simultaneous DSC-TG-MS.The kinetic parameters of PNIMMO decomposition was obtained from equation Kissinger and equation Ozawa.Equation Kissinge:E= 179.1 kJ.mol-1、lnA= 45.85s-1,equation Ozawa:E= 177.4kJ.mol-1、lnA= 39.19s-1。The mechanism functions of PNIMMO decomposition from equation Coats-Redfern was first order reaction.The PNIMMO decomposition gaseous products were studied,the mechanism of PNIMMO decomposition was analyzed.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.001
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.053
Threshold uncertainty score0.375

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0010.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.011
GPT teacher head0.260
Teacher spread0.249 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it