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Record W2382031851

New clean process for ammonium dichromate production

2013· article· en· W2382031851 on OpenAlexaff
Cnpc Key

Bibliographic record

VenueInorganic Chemicals Industry · 2013
Typearticle
Languageen
FieldMaterials Science
TopicCrystallization and Solubility Studies
Canadian institutionsL'Alliance Boviteq
Fundersnot available
KeywordsThermal decompositionChemistrySolubilityAmmonium carbonateAmmoniaPotassium dichromateAmmoniumDissolutionDecompositionInorganic chemistryNuclear chemistryOrganic chemistry
DOInot available

Abstract

fetched live from OpenAlex

A new clean process for production of ammonium dichromate was developed by recrystallizing the low-temperature thermal decomposition products of sodium chromate(Na2CrO4) and ammonium dichromate from a double salt crystal, NaNH4CrO4·2H2O obtained from the carbonation process of Na2CrO4 in ammonia solution.The solubility and phase diagram of Na2CrO4-(NH4)2Cr2O7-H2O system were determined.According to the solubility data and phase diagram,the recrystallizing separation process of thermal decomposition products to prepare ammonium dichromate was analyzed.Results showed that the high purity ammonium dichromate could be obtained by dissolving and cooling crystallizing the thermal decomposition pro- ducts at 100 ℃ and 50 ℃,respectively,and the yield of ammonium dichromate was 76.8%.Through ammonia still process,the mother solution could be reused,and the ammonia could be recycled in the process.Therefore,the process was cleaner and more environmentally friendly.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.001
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesInsufficient payload (model declined to judge)
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.031
Threshold uncertainty score0.998

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.001
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0030.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.026
GPT teacher head0.288
Teacher spread0.262 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations0
Published2013
Admission routes1
Has abstractyes

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