SYNTHESIS AND PROPERTIES OF N-VINYLCAPROLACTAM COPOLYMER MICROGELS CONTAINING β-CYCLODEXTRIN UNITS
Why this work is in the frame
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Bibliographic record
Abstract
VCL/GMA-EDA-β-CD copolymer microgels were synthesized by surfactant-free precipitation copolymerization of N-vinylcaprolactam(VCL) with a monovinyl β-CD monomer(GMA-EDA-β-CD) in aqueous solutions.The VCL/GMA-EDA-β-CD copolymer microgels were characterized via transmission electron microscopy(TEM),Fourier transfer infrared spectroscopy(FTIR),1H nuclear magnetic resonance(1H-NMR) and dynamic laser light scattering(DLS).The results indicate that addition of GMA-EDA-β-CD could reduce the particle size and size distribution of the copolymer microgels.The VCL/GMA-EDA-β-CD copolymer microgels exhibit thermally responsive changes in particle size in aqueous solutions,but incorporation of the β-CD monomer into a PVCL microgel could weaken its thermal sensitivity.
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Full frame distilled prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.001 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.000 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.000 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it