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Record W2387417403

Preparation of Supported Ni-B Amorphous Alloy Catalyst via New Chemical Reduction System and Its Catalytic Hydrogenation Properties

2006· article· en· W2387417403 on OpenAlexaff
Wu Qiu

Bibliographic record

Venuenot available
Typearticle
Languageen
FieldEngineering
TopicMetallic Glasses and Amorphous Alloys
Canadian institutionsCAE (Canada)
Fundersnot available
KeywordsChemistryCatalysisHydrazine (antidepressant)HydrateMethanolSodium borohydrideInorganic chemistrySolventBorohydridePotassiumAmorphous solidAlloySelectivityReducing agentNuclear chemistryOrganic chemistryChromatography
DOInot available

Abstract

fetched live from OpenAlex

The supported catalyst P1 was prepared with hydrazine hydrate and potassium borohydride as(co-reducers) in a mixed solvent consisting of methanol,ethanol and water in a proper proportion.The catalyst was a kind of nanosized amorphous alloy characterized by TEM,XRD and SAED.Catalyst P1 was used to(catalyze) the hydrogenation of o-chloronitrobenzene,and compared with the amorphous catalyst P2 prepared by the common method.As it is shown in the results,the activity and selectivity of P1 are slightly higher than those of P2,and the amount of potassium borohydride consumed in the preparation of P1 was only half of that in the preparation of P2.The effects of hydrazine hydrate,potassium borohydride,pH and solvent on the(properties) of the catalyst were also discussed.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.180
Threshold uncertainty score0.556

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.010
GPT teacher head0.200
Teacher spread0.190 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations0
Published2006
Admission routes1
Has abstractyes

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