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Record W2389667468

Study on the Thermolysis Properties of Polymers Containing n-Butyl Sulfonate Unit

2007· article· en· W2389667468 on OpenAlexaff
Jialing Pu

Bibliographic record

VenueYingxiang jishu · 2007
Typearticle
Languageen
FieldMaterials Science
TopicSynthesis and properties of polymers
Canadian institutionsL'Alliance Boviteq
Fundersnot available
KeywordsThermal decompositionSulfonateSulfonic acidDecompositionPolymerPolymer chemistryChemistryMethacrylateDissolutionMaterials scienceOrganic chemistryCopolymer
DOInot available

Abstract

fetched live from OpenAlex

In this study,thermolysis properties of a series of bipolymers with n-butyl p-styrenesulfonate(BPSS)and methyl methacrylate(MMA) in different ratio were investigated.By using DSC and IR,it was indicated that these bipolymers were thermo-decomposed at 200-240℃ and sulfonate unit could produce sulfonic acid in a relatively short time and its thermo-decomposition showed a self-acceleration effect.And further experiment results indicated that the thermo-decomposition energy of sulfonate unit largely reduced and the baking time of a polymer dissolving in neutral water also decreased when thermal acid generator was added,showing the polymers had a great affinity switch.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.002
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.028
Threshold uncertainty score0.611

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0020.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0010.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0010.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.076
GPT teacher head0.267
Teacher spread0.190 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations0
Published2007
Admission routes1
Has abstractyes

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