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Phosphate adsorption on metal oxides and metal hydroxides: A comparative review

2016· review· en· 380 citations· W2397945271 on OpenAlex· 10.1139/er-2015-0080

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A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.

Canadian venueIt was published in a Canadian venue.

No Canadian affiliation. An affiliation-only frame — the usual design — would never have seen this work. It is one of the works that make the case for inverting the frame.

Machine scores (provisional)

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Opus teacher head0.052
GPT teacher head0.311
Teacher spread
0.259 · how far apart the two teachers sit on this one work
Validation status
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Abstract

Phosphorus removal from wastewater is important for eutrophication control of water bodies. Metal oxides and metal hydroxides have always been developed and investigated for phosphorus removal, because of their abundance, low cost, environmental friendliness, and chemically stability. This paper presents a comparative review of the literature on the preparation methods, adsorption behaviors, adsorption mechanisms, and the regeneration of metal (hydr)oxides (e.g., Fe, Zn, Al, etc.) with regard to phosphate removal. The contrasting results showed that metal hydroxides could offer an effective and economic alternative to metal oxides, because of their cost–benefit synthesis methods, higher adsorption capacities, and shorter adsorption equilibrium times. However, the specific surface area of metal oxides is larger than that of metal hydroxides because of the calcination process. Metal oxides with a higher pH at the zero point of charge have wider optimal adsorption pH ranges than metal hydroxides because of their surface precipitation in alkaline solutions. The regeneration of metal oxides using acids, bases, and salts and that of metal hydroxides using acids and bases has been critically examined. Further research on uniform metal (hydr)oxides with small particle size, high stabilities, low cost, and that are easily regenerated with promising desorbents are proposed. In addition, quantitative mechanism study and application in continuous-mode column trials are also suggested.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

The record

Venue
Environmental Reviews
Topic
Phosphorus and nutrient management
Field
Environmental Science
Canadian institutions
Funders
Keywords
AdsorptionMetal hydroxideMetalLayered double hydroxidesInorganic chemistryCalcinationChemistryPoint of zero chargePhosphatePrecipitationHydroxideCatalysisOrganic chemistry
Has abstract in OpenAlex
yes