Artificial neural networks (ANNS) versus partial least squares (PLS) for spectral interference correction for taking part of the lab to the sample types of applications: an experimental study
Bibliographic record
Abstract
Interference and in particular spectral interference is a well documented problem in optical emission spectrometry. For example, it is commonly encountered even when commercially-available spectrometers with medium to high resolution are used (e.g., those with focal lengths of 0.75 m to 1 m). Such interference must be corrected. Although portable spectrometers are better suited for <i>"taking part of the lab to the sample"</i> types of applications, the effects of interference become more pronounced due to the short focal length of such spectrometers (e.g., 10 cm to 15 cm). We describe use of Artificial Neural Networks (ANNs) and of Partial Least Squares (PLS) methods for spectral interference correction.
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How this classification was reachedexpand
Full frame distilled prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.001 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.001 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.000 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from itClassification
machine, unvalidatedMachine predicted; a candidate call from one teacher head, not a consensus.
How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".