Highly Efficient Dual-Color Electrochemiluminescence from BODIPY-Capped PbS Nanocrystals
Why this work is in the frame
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Bibliographic record
Abstract
Electrochemiluminescence (ECL) of a hybrid system consisting of PbS nanocrystals (NCs) and a BODIPY dye (BDY) capping ligand was discovered to produce highly efficient dual emissions with tri-n-propylamine as a coreactant. By means of spooling ECL spectroscopy, the strong dual ECL emission peaks of 984 and 680 nm were attributed to the PbS and BDY moieties, respectively, and found to be simultaneous during the light evolution and devolution. The ECL of the PbS was enhanced via NC collisions with the electrode and reached an efficiency of 96% relative to that of Ru(bpy)3(2+), which is the highest among the semiconductor NCs.
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Full frame distilled prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.001 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.000 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.000 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it