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Titanium Dioxide‐Mediated Photocatalytic Degradation of Humic Acid under Natural Sunlight

2012· article· en· W2415569393 on OpenAlex

Why this work is in the frame

A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.

affAt least one author lists a Canadian institution in the pinned OpenAlex snapshot.

Bibliographic record

VenueWater Environment Research · 2012
Typearticle
Languageen
FieldEnergy
TopicTiO2 Photocatalysis and Solar Cells
Canadian institutionsLakehead University
FundersNational University of Singapore
KeywordsHumic acidPhotocatalysisChemistryTitanium dioxideAdsorptionMineralization (soil science)Dissolved organic carbonDegradation (telecommunications)CatalysisOrganic matterNuclear chemistryEnvironmental chemistryInorganic chemistryChemical engineeringOrganic chemistry

Abstract

fetched live from OpenAlex

In this article, photocatalytic degradation of humic acid, a predominant type of natural organic matter present in ground and surface waters, was conducted using a commercial titanium dioxide catalyst under natural sunlight irradiation in a batch photoreactor. Various parameters, such as photocatalyst loading, pH value, irradiation intensity, initial concentration, and illumination time, had a significant influence on humic acid removal. The adsorption isotherm of TiO2 dosage fit to Langmuir's isotherm equation well, and the reaction kinetics of initial dissolved organic carbon (DOC) concentration increased with the increase of TiO2 dosage but decreased with the increase of initial DOC. The mineralization of humic acid revealed that the large molecular weight organics with aromatic and hydrophobic properties were removed, while the most persistent components were the shortest UV-absorbing and hydrophilic low-molecular-weight compounds. This study indicates that the solar/ TiO2 photocatalytic degradation is a promising process for humic acid removal from water.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.001
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesInsufficient payload (model declined to judge)
Consensus categoriesInsufficient payload (model declined to judge)
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.027
Threshold uncertainty score0.998

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0010.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0020.004

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.037
GPT teacher head0.280
Teacher spread0.243 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it