PLASMA SURFACE MODIFIED POLYTETRAFLUOROETHYLENE GRAFTED NANOLAYERS AND COMPLEXES THEREFROM
Bibliographic record
Abstract
Metal complexes of copolymers based on poly(acrylic acid), poly(4-vinylpyridine) and poly(1-vinylimidazole) plasma grafted onto films of poly(tetrafluoroethene) were prepared by complex formation with solutions of salts of FeCl3.6H2O, CuCl2.2H2O, CoCl2.6H2O, VOSO4.5H2O and Na2MoO4.2H2O at room temperature. The introduction of metal ions was found to depend mainly on the degree of grafting of acrylic acid, 4-vinylpyridine and 1-vinylimidazole and was from 1.1 tо 6.5 mg metal ion/g polymer carrier. The studies carried out by IR spectroscopy, Moessbauer spectroscopy and electron paramagnetic resonance proved the preparation of metal complexes.
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How this classification was reachedexpand
Full frame machine prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.
Distilled classifier scores by category (both heads)
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.000 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.001 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from itClassification
machine, unvalidatedMachine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.
How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".