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Record W2421738929 · doi:10.18268/bsgm2009v61n3a3

Modelo teórico para el cálculo de las solubilidades mutuas entre gases no-polares y agua con sales disueltas

2009· article· es· W2421738929 on OpenAlexaff
Renee J. Pérez, Robert A. Heidemann, Eduardo Gonzáléz-Partida

Bibliographic record

VenueBoletín de la Sociedad Geológica Mexicana · 2009
Typearticle
Languagees
FieldEngineering
TopicPhase Equilibria and Thermodynamics
Canadian institutionsUniversity of Calgary
Fundersnot available
KeywordsHumanitiesPhysicsPhilosophy

Abstract

fetched live from OpenAlex

En el presente artculo se propone un modelo terico para el clculo del equilibrio qumico de fases entre gases no-polares y agua. Este modelo es aplicable completamente a sistemas acuosos puros o con sales disueltas. En ambos casos el modelo proporciona predicciones vlidas hasta 647 K, presiones de hasta 2 kilo-bares, y concentraciones de sales disueltas iguales a la saturacin del slido mineral. El modelo termodinmico hace uso de una ecuacin de estado para reproducir datos experimentales en todas las fases excepto en la fase lquida del agua. Para esta ltima se utiliza la constante de Henry. En el caso de la presencia de sales, el potencial qumico del soluto gas en la fase lquida del agua est relacionada al potencial qumico del soluto en la salmuera a travs del coeficiente de Setschenov. Estos coeficientes se pueden derivar de datos experimentales de solubilidad. Con el modelo se pueden reproducir todos los fenmenos de solubilidad cruciales, incluyendo el equilibrio entre tres fases. Sin embargo con las ecuaciones propuestas no se pueden reproducir los fenmenos gas-gas que ocurren en la vecindad del punto crtico del agua ni

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.001
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesMeta-epidemiology (narrow)
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Simulation or modeling · Consensus signal: none
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.652
Threshold uncertainty score0.999

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0010.000
Meta-epidemiology (narrow)0.0010.001
Meta-epidemiology (broad)0.0010.001
Bibliometrics0.0000.000
Science and technology studies0.0000.001
Scholarly communication0.0010.000
Open science0.0010.000
Research integrity0.0010.001
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.007
GPT teacher head0.259
Teacher spread0.252 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

Study designSimulation or modeling
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations1
Published2009
Admission routes1
Has abstractyes

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