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Record W2462852943 · doi:10.1021/ie0401861

Oxidation of SO<sub>2</sub> and Recovery of SO<sub>3</sub> Using Nonaqueous Solvents

2005· article· en· W2462852943 on OpenAlexaff
Napapan Wattanakasemtham, Eric Croiset, R. R. Hudgins, P.L. Silveston, Ali Lohi

Bibliographic record

VenueIndustrial & Engineering Chemistry Research · 2005
Typearticle
Languageen
FieldEngineering
TopicPhase Equilibria and Thermodynamics
Canadian institutionsToronto Metropolitan UniversityUniversity of Waterloo
Fundersnot available
KeywordsSupercritical fluidChemistryActivated carbonDesorptionSupercritical carbon dioxideDegradation (telecommunications)Carbon fibersOrganic chemistryInorganic chemistryAdsorptionMaterials science

Abstract

fetched live from OpenAlex

An earlier study from our laboratory using nonaqueous solvents to increase the concentration of acid recovered from adsorbing and reacting SO 2 to form SO 3 on activated carbon is extended to additional organic solvents and the use of subcritical and supercritical CO 2 . However, our conclusion from the previous work that organic solvents make suitable flushing agents is contradicted because of the degradation of some solvents or the discoloration of the acid product. Desorption of SO 3 from activated carbon using supercritical CO 2, however, is satisfactory. A statistically designed study showed that the temperature, pressure, and superficial velocity of CO 2 fed to the carbon bed control the recovery.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.002
Threshold uncertainty score0.004

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0010.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.043
GPT teacher head0.279
Teacher spread0.236 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations1
Published2005
Admission routes1
Has abstractyes

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