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Record W2482619727 · doi:10.1520/mnl11427m

Chapter 7: Distillation and Vapor Pressure Data of Crude Oil

2008· book-chapter· en· W2482619727 on OpenAlexaff
Rey G. Montemayor

Bibliographic record

Venuenot available
Typebook-chapter
Languageen
FieldChemistry
TopicPetroleum Processing and Analysis
Canadian institutionsImperial Oil (Canada)
Fundersnot available
KeywordsDistillationCrude oilPetroleum engineeringVapor pressureEnvironmental scienceProcess engineeringChemistryChromatographyOrganic chemistryEngineering

Abstract

fetched live from OpenAlex

CRUDE OIL IS A HIGHLY COMPLEX MIXTURE OF MOlecular species made up of hydrogen and carbon (commonly referred to as hydrocarbons), heterocyclic molecular species (hydrocarbons with cyclic structures containing other chemical species such as oxygen, nitrogen, or sulfur or a combination thereof), organometallic compounds (hydrocarbons containing metal chemical species), inorganic sediments, and water. Crude oil can vary greatly in composition, and can exhibit highly variable physical and chemical characteristics. This is due to the fact that crude oils are not pure materials, but usually contain colloidally suspended components, dispersed solids, and emulsified water. No two crude oils will be chemically or physically identical. The composition of crude oil can vary from highly flammable light ends to highly viscous and heavy tar-like materials. The chemical composition of crude oil varies from field to field, between regions, and even within the same geologic formation. The physical and chemical analyses of crude oil to determine its quality and processability is known as a crude oil assay. The results of a crude oil assay testing can provide extensive detailed data useful for refiners, oil traders, and producers. Assay data can help refineries determine if a crude oil is compatible for a particular petroleum refiner, or if the crude oil can cause yield, quality, production, environmental, and other problems. To determine the desired information, two different analytical schemes are commonly used, namely an inspection assay and a comprehensive assay. Inspection assays generally involve a few limited properties such as API gravity or density, sulfur content, sediment, and water. Occasionally pour point is determined to determine the fluidity of the crude oil. There is very limited agreement on what constitutes an inspection assay. Different oil companies generally do additional tests that will provide information that can be used in the processing of a given crude oil. Comprehensive assays involve more tests than what are performed on an inspection assay. The overriding issue in doing a comprehensive assay on a given crude oil is economics. Comprehensive assays of crude oil are done to determine: (a) the slate of products that can be produced with a given refinery's process technology, (b) processing difficulties that may arise as a result of the inherent composition and impurities of the crude oil, and (c) downstream processing and upgrading activities to optimize yields of high-value products. Since this manual is concerned mainly with distillation and vapor pressure measurements of crude oil, the focus of this chapter is on the distillation and vapor pressure data. There are a number of other tests which are performed during an inspection assay or a comprehensive assays. These are discussed in detail elsewhere [1].

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.001
metaresearch head score (Gemma)0.001
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Not applicable · Consensus signal: none
GenreCandidate signal: Dataset · Consensus signal: none
Teacher disagreement score0.029
Threshold uncertainty score0.098

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0010.001
Meta-epidemiology (narrow)0.0010.001
Meta-epidemiology (broad)0.0010.001
Bibliometrics0.0030.003
Science and technology studies0.0010.000
Scholarly communication0.0010.001
Open science0.0010.001
Research integrity0.0010.001
Insufficient payload (model declined to judge)0.0290.022

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.036
GPT teacher head0.247
Teacher spread0.212 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designNot applicable
Domainnot available
GenreDataset

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations2
Published2008
Admission routes1
Has abstractyes

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