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Record W2490427618

Femtosecond Laser Interaction with Graphene Oxide Aqueous Solution

2015· dissertation· en· W2490427618 on OpenAlexfundno aff
Khaled H. Ibrahim

Bibliographic record

VenueUWSpace (University of Waterloo) · 2015
Typedissertation
Languageen
FieldEngineering
TopicLaser-Ablation Synthesis of Nanoparticles
Canadian institutionsnot available
FundersUniversity of Waterloo
KeywordsGrapheneOxideMaterials scienceAqueous solutionX-ray photoelectron spectroscopyLaserSurface roughnessGraphene oxide paperAnalytical Chemistry (journal)Thin filmFemtosecondNanotechnologyChemical engineeringOpticsComposite materialChemistryChromatographyOrganic chemistry
DOInot available

Abstract

fetched live from OpenAlex

In this study fs pulsed laser of wavelength 800 nm was used to reduce two sets of aqueous graphene oxide solution namely low (0.5 mg/mL) and high concentration (6.2 mg/mL). It was found that after fs laser treatment the surface roughness of the graphene oxide flakes was reduced by 95.6% and 66% for the high and low GO concentration films respectively. It was also found that the resistivity of high concentration (6.2 mg/ml) rGO films was enhanced by 4 orders of magnitude as a result of the laser treatment which could raise the electron mobility of the rGO films close to that of pristine graphene films. The C-O atomic ratio for the high concentration graphene oxide samples was found to increase by 3 times after 6 hrs of laser treatment. \nA novel technique of graphene oxide sol-gel (GOSG) fabrication was introduced where GOSG was obtained by placing the laser focal point at the solution/air interface. By manipulating the exposure parameters such as the ablated volume, laser energy and focal length, the GOSG was obtained at various times in the range of as 8 min to 7 hrs. The chemical analysis (XPS) revealed the reduction of the COOH molecules as a result of the exposure process, which is due to removing the OH- from the GO sheets and vaporization of the water content within the solution. Surface morphology analysis using AFM and SEM showed that all GOSG thin films except the 7 hrs one depicted a high surface roughness and porous surface area with randomly stacked graphene oxide layers. However, a smooth stacking layered structure and the smallest average surface roughness was observed in the 7 hrs GOSG, which was pertained the behavior of pure graphene as proved by the FTIR analysis.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.003
Threshold uncertainty score0.009

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0030.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.011
GPT teacher head0.191
Teacher spread0.181 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations2
Published2015
Admission routes1
Has abstractyes

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