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Record W2493866611 · doi:10.1021/bk-2001-0773.ch016

Polychlorinated Naphthalenes in the Atmosphere

2000· book-chapter· en· W2493866611 on OpenAlexaff
Tom Harner, Terry F. Bidleman, Robert G. M. Lee, Kevin C. Jones

Bibliographic record

VenueACS symposium series · 2000
Typebook-chapter
Languageen
FieldEnvironmental Science
TopicToxic Organic Pollutants Impact
Canadian institutionsEnvironment and Climate Change Canada
Fundersnot available
KeywordsAtmosphere (unit)Partition coefficientEnvironmental chemistryEnvironmental scienceSink (geography)ArcticParticle (ecology)Atmospheric sciencesChemistryMeteorologyGeographyOrganic chemistryPhysicsEcologyBiologyCartography

Abstract

fetched live from OpenAlex

Polychlorinated naphthalenes (PCNs) are a class of industrial chemicals that are receiving renewed interest due to their abundance in the atmosphere and dioxin-like toxicity. Several recent measurements of their atmospheric burdens show that ΣPCN is 60-150 pg m-3 at urban locations and lower at rural and remote sites. Typically, ΣPCN is 20-50% of ΣPCB (polychlorinated biphenyls) and the toxicity contribution (measured as TCDD toxic equivalents, TEQs) is of a similar magnitude. Air parcel back trajectories show that elevated PCN burdens at remote arctic locations can be attributed to air masses that stem from land-based sources in the U.K. and Europe. The long-range atmospheric transport of PCNs is largely governed by particle-gas partitioning. The particle-associated fraction of PCNs is described using a simple model that utilizes the octanol-air partition coefficient (KOA).

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesMeta-epidemiology (narrow), Insufficient payload (model declined to judge)
Consensus categoriesInsufficient payload (model declined to judge)
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Not applicable · Consensus signal: none
GenreCandidate signal: Other · Consensus signal: none
Teacher disagreement score0.855
Threshold uncertainty score1.000

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0010.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0170.003

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.009
GPT teacher head0.203
Teacher spread0.194 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; both teacher heads agree on what is shown here.

Study designNot applicable
Domainnot available
GenreOther

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations4
Published2000
Admission routes1
Has abstractyes

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