FAR INFRARED SYNCHROTRON SPECTRUM OF TRIMETHLYENE OXIDE
Bibliographic record
Abstract
Rotationally-resolved vibrational spectra of trimethlyene oxide (c-C$_{3}$H6O) from 650 through 1200 \\wn were recorded using far infrared synchrotron radiation at the Canadian Light Source with better than 0.001 \\wn resolution. The observed bands correspond to at least eight different fundamental vibrations in this region. Due to the low frequency ring puckering motion,\\footnote{G. Moruzzi \\textit{et al.}, \\underline{J. Mol. Spectrosc.} \\bf{219}, 152 (2003).} the observed rovibrational pattern of each band is congested with hot-combination bands that originate in the first two excited ring puckering states (52.9 \\wn, 142.6 \\wn). The ongoing analysis of the strong \\textit{b-type} bands corresponding to asymmetric in-plane CO stretching ($\\nu$$_{10}$:1008 \\wn)\\footnote{B\\'{a}nhegyi \\textit{et al.} \\underline{Spectrochim. Acta.} \\bf{39A}, 761 (1983).} will be discussed along with the identification of allowed Coriolis interactions arising from nearby energy levels related to in-plane CC stretching ($\\nu$$_{9}$: 940 \\wn, $\\nu$$_{3}$: 1033 \\wn).
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How this classification was reachedexpand
Full frame machine prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.
Distilled classifier scores by category (both heads)
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.000 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.006 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from itClassification
machine, unvalidatedMachine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.
How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".