CHIRPED PULSE MICROWAVE SPECTROSCOPY IN PULSED UNIFORM SUPERSONIC FLOWS: OBSERVATION OF K-DEPENDENT RATES IN THE CL + PROPYNE REACTION
Bibliographic record
Abstract
Chirped-Pulse Fourier-transform microwave spectroscopy in uniform supersonic flows (CPUF) \nhas been applied to study the reaction of Cl atoms with propyne. The approach utilizes broad-band microwave spectroscopy to extract structural information with MHz resolution and near universal detection, in conjunction with a Laval flow system, which offers thermalized conditions at low temperatures and high number densities. Our previous studies have exploited this approach to obtain multichannel product branching fractions in a number of polyatomic systems, with isomer and often vibrational level specificity. This report highlights an additional capability of the CPUF technique: here, the state-specific reactant depletion is directly monitored on a microsecond timescale. In doing so, a clear dependence on the rotational quantum number K in the rate of the reaction between Cl atoms and propyne is revealed. Future prospects for the technique will be discussed.
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How this classification was reachedexpand
Full frame machine prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.
Distilled classifier scores by category (both heads)
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.000 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.001 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from itClassification
machine, unvalidatedMachine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.
How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".