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Record W2516737083 · doi:10.5539/jmsr.v5n4p22

Deactivation Mechanism of Titania Catalyst

2016· article· en· W2516737083 on OpenAlexvenueno aff
Mansour A. Al-Shafei, Ahmed K. A. AlAsseel, Abdulhadi M. Adab, Hasan A. Al-Jama, Amer A. Al-Tuwailib, Shouwen Shen

Bibliographic record

VenueJournal of Materials Science Research · 2016
Typearticle
Languageen
FieldEngineering
TopicCatalysis and Hydrodesulfurization Studies
Canadian institutionsnot available
Fundersnot available
KeywordsCatalysisMaterials scienceChemical engineeringCatalyst poisoningMechanism (biology)RunwaySulfurCatalyst supportMetallurgyChemistryOrganic chemistryEngineering

Abstract

fetched live from OpenAlex

<p class="1Body">Catalyst deactivation is a well-recognized phenomenon in the petroleum and chemical processing industries. Identifying the root causes of this phenomenon is an important factor for enhancing catalyst efficiency and preventing undesirable failures. In this study, state-of-the-art instruments were utilized to investigate the causes of catalyst deactivation that led to the replacement of the catalyst bed in one of the sulfur recovery units at a Saudi Aramco gas plant. Titania catalysts have been examined to determine the inherent deactivation mechanism and also to find out the possibilities of its curement. Understanding the root cause of the deactivation is mandatory for field engineers to minimize future catalyst deactivation. The collected analysis data revealed that the deactivation mechanism occurred for the Ti catalyst due to irreversible chemical phase transformation of the catalyst caused by a temperature runway in the catalytic converter.</p>

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.004
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.004
Threshold uncertainty score0.138

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0040.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.001
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.055
GPT teacher head0.339
Teacher spread0.285 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations2
Published2016
Admission routes1
Has abstractyes

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