Supramolecular Microgels Fabricated from Supramonomers
Why this work is in the frame
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Bibliographic record
Abstract
This letter describes a new method for fabricating supramolecular microgels from supramonomers. To this end, we designed and assembled supramonomers with one acrylate moiety on each end on the basis of noncovalent host–guest interactions, which could be utilized as a cross-linker. Then supramolecular microgels were fabricated through the copolymerization of supramonomers and N -isopropylacrylamide (NIPAm). The supramolecular microgels not only showed temperature-responsive properties as expected from conventional PNIPAm-based microgels but also exhibited stimuli-responsive and degradable properties benefiting from the dynamic nature of supramonomers. In addition, it was found that the degradation kinetics of the supramolecular microgels was related greatly to the structure of the microgels, providing a way to tune the degradation kinetics of the supramolecular microgels. Various supramolecular microgels with desired structure and function are supposed to be facilely fabricated from supramonomers. It is anticipated that the supramolecular microgels can enrich the application of microgels by easily endowing the microgels with stimuli-responsive and degradable properties.
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Full frame distilled prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.001 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.001 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.001 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.002 | 0.006 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it