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Record W2523074965 · doi:10.1021/acsomega.6b00177

Improving the Sunscreen Properties of TiO<sub>2</sub> through an Understanding of Its Catalytic Properties

2016· article· en· W2523074965 on OpenAlex

Why this work is in the frame

A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.

affAt least one author lists a Canadian institution in the pinned OpenAlex snapshot.
fundA Canadian funder is recorded on the work.

Bibliographic record

VenueACS Omega · 2016
Typearticle
Languageen
FieldEnergy
TopicTiO2 Photocatalysis and Solar Cells
Canadian institutionsUniversity of Ottawa
FundersErasmus+European CommissionNatural Sciences and Engineering Research Council of CanadaCanada Research ChairsEducation, Audiovisual and Culture Executive AgencyCanada Foundation for Innovation
KeywordsRadicalTitanium dioxideBiocompatible materialPhotocatalysisCatalysisNanotechnologyChemistryPhotochemistryMaterials scienceChemical engineeringOrganic chemistryComposite material

Abstract

fetched live from OpenAlex

High Resolution Image Download MS PowerPoint Slide The use of particulate titanium dioxide (TiO 2 ) as an active sunscreen ingredient has raised concerns about potential risks from TiO 2 -mediated free radical formation. To date, remediation attempts have concentrated on reducing the yield of free radical generation by TiO 2 upon sunlight exposure. The problem with this approach is that given the band gap in TiO 2, production of radical and the ensuing reactive oxygen species (ROS) is completely normal. Our strategy is based on a nontoxic, biocompatible shell that neutralizes the free radicals by scavenging them with natural antioxidants before they exit the particle. The new lignin@TiO 2 composites preserve the scattering and absorption properties of TiO 2 because the particles retain their nanoscale dimensions as preferred by the cosmetic industry. Although the target properties for photocatalysis and sun-protection applications are opposite, we argue that exactly the same knowledge is required to optimize either one.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.009
Threshold uncertainty score0.397

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.001
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.063
GPT teacher head0.224
Teacher spread0.161 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it