1,2,4‐Triazol‐5‐ylidenes versus Imidazol‐2‐ylidenes for the Stabilization of Phosphorus(I) Cations
Why this work is in the frame
A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.
Bibliographic record
Abstract
The synthesis and characterization of a series of 1,4‐dialkyl‐1,2,4‐triazolium iodide and tetraphenylborate salts featuring methyl, ethyl, and isopropyl substituents and their use as precursors, in conjunction with triphosphenium reagents, to generate 1,4‐dialkyl‐1,2,4‐triazol‐5‐ylidene‐stabilized phosphorus(I) ions is described. The use of tetraphenyl borate salts of both reagents produces the most pure products. The structural and spectroscopic features of the products are compared to those of analogous ions featuring 1,3‐imidazol‐2‐ylidene ligands.
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Full frame distilled prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.002 |
| Meta-epidemiology (narrow) | 0.001 | 0.000 |
| Meta-epidemiology (broad) | 0.001 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.001 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.004 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it