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Record W2525338126 · doi:10.1109/redec.2016.7577544

Preparation and characterization of Ni-Co-Mg-Al mixed oxides derived from layered double hydroxides and their performance in the dry reforming of methane

2016· article· en· W2525338126 on OpenAlexfundno aff
Carole Tanios, Sandy Bsaibes, Mira Nawfal, Cédric Gennequin, Haingomalala Lucette Tidahy, Antoine Aboukaı̈s, Edmond Abi‐Aad, Madona Labaki, B. Nsouli

Bibliographic record

Venuenot available
Typearticle
Languageen
FieldChemical Engineering
TopicCatalysts for Methane Reforming
Canadian institutionsnot available
FundersAgence Universitaire de la FrancophonieUniversité du Littoral Côte d'Opale
KeywordsHydrotalciteCalcinationCatalysisThermogravimetric analysisCarbon dioxide reformingMethaneMaterials scienceDifferential scanning calorimetryNuclear chemistryFourier transform infrared spectroscopyChemical engineeringSyngasChemistryAnalytical Chemistry (journal)Organic chemistryPhysicsThermodynamics

Abstract

fetched live from OpenAlex

The hydrotalcite route was used to prepare Ni and Co oxides catalysts, with different Ni/Co contents. The catalytic performance of these oxides was investigated with the dry reforming of methane in order to produce energy vector from renewable energy. The samples were characterized, before and after calcination, by X-ray diffraction (XRD), differential scanning calorimetry (DSC), thermogravimetric analysis (TG), Fourier Transform Infrared spectroscopy (IR), and determination of the specific surfaces by the BET method. After calcination at 800 °C under an air flow, the hydrotalcite structure was completely decomposed. The dry reforming of methane was carried out using a mixture of CH <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">4</sub> :CO <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">2</sub> (1:1) after 2 hours of reduction under an H <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">2</sub> flow at 800 °C. Ni-Co based catalysts revealed better catalytic activity than the Co based one.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.013
Threshold uncertainty score0.288

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.014
GPT teacher head0.243
Teacher spread0.229 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations4
Published2016
Admission routes1
Has abstractyes

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