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Efficient Blue Electroluminescence Using Quantum-Confined Two-Dimensional Perovskites

2016· article· en· 356 citations· W2527247329 on OpenAlex· 10.1021/acsnano.6b05775

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Opus teacher head0.010
GPT teacher head0.223
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Validation status
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Abstract

Solution-processed hybrid organic-inorganic lead halide perovskites are emerging as one of the most promising candidates for low-cost light-emitting diodes (LEDs). However, due to a small exciton binding energy, it is not yet possible to achieve an efficient electroluminescence within the blue wavelength region at room temperature, as is necessary for full-spectrum light sources. Here, we demonstrate efficient blue LEDs based on the colloidal, quantum-confined 2D perovskites, with precisely controlled stacking down to one-unit-cell thickness (n = 1). A variety of low-k organic host compounds are used to disperse the 2D perovskites, effectively creating a matrix of the dielectric quantum wells, which significantly boosts the exciton binding energy by the dielectric confinement effect. Through the Förster resonance energy transfer, the excitons down-convert and recombine radiatively in the 2D perovskites. We report room-temperature pure green (n = 7-10), sky blue (n = 5), pure blue (n = 3), and deep blue (n = 1) electroluminescence, with record-high external quantum efficiencies in the green-to-blue wavelength region.

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The record

Venue
ACS Nano
Topic
Perovskite Materials and Applications
Field
Engineering
Canadian institutions
Funders
Queen's UniversityEngineering and Physical Sciences Research CouncilEidgenössische Technische Hochschule ZürichFlorida State UniversitySun Yat-sen UniversityDivision of Materials ResearchQueen's University BelfastNational Sun Yat-sen UniversityNational Science Foundation
Keywords
ElectroluminescenceMaterials scienceExcitonLight-emitting diodeOptoelectronicsBlueshiftQuantum efficiencyDielectricQuantum dotQuantum wellHalideDiodePhotoluminescenceNanotechnologyOpticsChemistryPhysicsCondensed matter physicsInorganic chemistry
Has abstract in OpenAlex
yes