Crystal structure of <i>catena</i>-poly[bis(tetraethylammonium) [tetraaquatris(μ-dicyanamido-κ<sup>2</sup> <i>N</i> <sup>1</sup>:<i>N</i> <sup>5</sup>)bis(dicyanamido-κ<i>N</i> <sup>1</sup>)dicobaltate(II)] dicyanamide]
Bibliographic record
Abstract
The structure of the title compound, [N(C 2 H 5 ) 4 ] 2 [Co 2 (C 2 N 3 ) 5 (H 2 O) 4 ](C 2 N 3 ), is a new example of a metal–dicyanamide coordination polymer which exhibits a unique three-dimensional framework of covalently linked Co II chains. All bridging dicyanamide ligands in the title structure are in the μ 1,5 -bridging mode. The anionic Co II -dicyanamide network is templated by tetraethylammonium cations residing in a series of channels extending along the b axis where additional non-coordinating dicyanamidate anions are also located. The framework structure is further stabilized by O—H...N hydrogen bonding between aqua ligands and dicyanamido ligands or the dicyanamide anion. In addition, C—H...N interactions are present between the tetraethylammonium cations and dicyanamide amide nitrogen atoms.
Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.
How this classification was reachedexpand
Full frame distilled prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.003 | 0.002 |
| Meta-epidemiology (narrow) | 0.004 | 0.004 |
| Meta-epidemiology (broad) | 0.005 | 0.004 |
| Bibliometrics | 0.005 | 0.013 |
| Science and technology studies | 0.006 | 0.008 |
| Scholarly communication | 0.001 | 0.003 |
| Open science | 0.011 | 0.004 |
| Research integrity | 0.005 | 0.007 |
| Insufficient payload (model declined to judge) | 0.005 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from itClassification
machine, unvalidatedMachine predicted; both teacher heads agree on what is shown here.
How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".