Multistage dolomitization in the Qal'eh Dokhtar Formation (Middle‐Upper Jurassic), Central Iran: petrographic and geochemical evidence
Bibliographic record
Abstract
The late Jurassic Qal'eh Dokhtar Formation lithologically comprises three parts, from bottom to top, a lower sandstone unit, middle shale unit and an upper carbonate unit, which extend in a N–S direction over a wide area to the east of the Shotori Range and west of the Lut Block (Central Iran). This succession was deposited on a mixed carbonate–siliciclastic ramp. Carbonate rocks of the Qal'eh Dokhtar Formation vary from undolomitized, to partly dolomitized, to completely dolomitized. Field observations from two measured sections (the type section, 955 m thick, and the Sorond section, 639 m thick), combined with detailed petrographic and geochemical analyses, revealed the diverse types of dolomite in this formation. Five types of replacement dolomite and one type of dolomite cement were distinguished. Replacement dolomites (RD) consist of: (1) fine crystalline planar‐s (RD1); (2) medium crystalline planar‐s (RD2); (3) medium crystalline planar‐e (RD3); (4) coarse crystalline planar‐s (RD4); and (5) coarse crystalline planar‐e (RD5). Coarse crystalline planar dolomite cements (DC) were observed in low abundance and filling dissolution voids and fractures. Variation in dolomite types is mainly related to early to late diagenetic processes leading to changes in composition of the dolomitizing fluids. Replacement dolomites are non‐stoichiometric (Ca43‐56–Mg34‐45) with Sr, Mn and Fe concentrations of 41–138 ppm, 168–919 ppm and 5000–21000 ppm, respectively. These dolomites are characterized by δ18O values ranging from 0.0 to –11.8 ‰ VPDB and δ13C values of +1.1 to +3.2 ‰ VPDB. These values are depleted in δ18O relative to the postulated values for late Jurassic dolomites precipitated in equilibrium with seawater, while δ13C values are within the range of Jurassic seawater dolomite values. Fluid inclusion data of RD4, RD5 and DC yield homogenization temperatures of 72 to 118 °C. Based on petrographic, fluid inclusion microthermometric data and geochemical results, the replacement dolomites in the Qal'eh Dokhtar Formation are interpreted to have formed in the subsurface at shallow to intermediate burial depths. These dolomites were then recrystallized at increased burial depths and temperatures. Seawater was the major source of Mg2+ for early diagenetic dolomite (DR1), while Mg2+ for late diagenetic dolomites was provided from diagenesis of clay minerals in shales and mechanical compaction of mudstone in the Qal'eh Dokhtar Formation. The dolomite cement is postdated by coarsely crystalline mosaic calcite cement indicating that diagenetic fluids eventually became undersaturated with respect to dolomite and oversaturated with respect to calcite. Copyright © 2016 John Wiley & Sons, Ltd.
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How this classification was reachedexpand
Full frame machine prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.
Distilled classifier scores by category (both heads)
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.004 | 0.002 |
| Science and technology studies | 0.001 | 0.001 |
| Scholarly communication | 0.001 | 0.000 |
| Open science | 0.000 | 0.001 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.001 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from itClassification
machine, unvalidatedMachine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.
How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".