Thieme Chemistry Journals Awardees – Where Are They Now? What’s Golden: Recent Advances in Organic Transformations Using Photoredox Gold Catalysis
Why this work is in the frame
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Bibliographic record
Abstract
Light-mediated photoredox transformations have become commonplace in contemporary catalysis research and design. Excited-state redox catalysts trigger photoinduced electron transfers (PET) through oxidative or reductive quenching modes, allowing access to one-electron variations of classic radical reactions and the discovery of new transformations in organic chemistry. Herein, the use of Au-based photoredox catalysts containing powerful redox properties along with the emergence of dual catalyzed organic transformations involving photoredox catalysis and Au complexes for the Au(I)/Au(III) redox couple without use of stoichiometric oxidants will be discussed. 1 Principles of Photochemistry and Gold 2 Photoredox Transformations with Dimeric Gold Complexes 3 Dual Catalysis Involving Au(I)/Au(III) Redox Cycles 4 Concluding Remarks
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Full frame distilled prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.002 |
| Open science | 0.000 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.007 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it