Energetics of reactions in a dielectric barrier discharge with argon carrier gas: V hydrocarbons
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Bibliographic record
Abstract
We report dielectric barrier discharge (DBD)‐based atmospheric pressure (AP) plasma polymerization (PP) experiments using argon carrier gas and a wide variety of hydrocarbon molecules as the precursors (“monomers”). As in our preceding research with other reagents, unprecedented precision and reproducibility in energy measurements is again demonstrated. Measurements based on various aliphatic and aromatic hydrocarbon compounds have yielded values of E m , the energy absorbed from the plasma by each monomer molecule. Systematic differences among families of compounds enabled us to draw several important conclusions about fragmentation and polymerization in the DBD plasma environment, observations which are in fair qualitative agreement with low‐pressure radio‐frequency PP data by Yasuda and Hirotsu from the 1970s.
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Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.000 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.000 | 0.000 |
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Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
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