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Record W2553195805 · doi:10.1002/cjce.22735

A new straightforward method for measuring xylene soluble for high impact polypropylene

2016· article· en· W2553195805 on OpenAlexvenueno aff
Olivier Boyron, Aarón J. Cancelas, Manel Taam, Christophe Boisson, Timothy F. L. McKenna

Bibliographic record

VenueThe Canadian Journal of Chemical Engineering · 2016
Typearticle
Languageen
FieldMaterials Science
TopicPolymer crystallization and properties
Canadian institutionsnot available
Fundersnot available
KeywordsPolypropyleneGravimetric analysisNatural rubberFraction (chemistry)SolventPolymerXyleneProcess engineeringExtraction (chemistry)Volume fractionVolume (thermodynamics)Materials sciencePolymer scienceComputer scienceChromatographyChemistryComposite materialOrganic chemistryEngineeringThermodynamicsPhysics

Abstract

fetched live from OpenAlex

Abstract The determination of the xylene soluble fraction in high impact polypropylene is used to estimate the rubber content in the polymer material. In analytical laboratories, the soluble fraction is measured by solvent extraction using gravimetric methods according to ASTM5492 or ISO6427. These methods require a large quantity of polymers, large volume of solvent, and long extraction times. It is therefore highly desirable to develop other laboratory methodologies for this task; preferably methodologies that employ existing laboratory equipment. It is found that the SEC method proposed here yields estimates of rubber contents very close to those found using standardized technics but in much shorter times.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.001
metaresearch head score (Gemma)0.001
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: none
Teacher disagreement score0.003
Threshold uncertainty score0.009

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0010.001
Meta-epidemiology (narrow)0.0010.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0010.001
Science and technology studies0.0000.000
Scholarly communication0.0000.001
Open science0.0010.000
Research integrity0.0010.001
Insufficient payload (model declined to judge)0.0030.002

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.024
GPT teacher head0.239
Teacher spread0.215 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations10
Published2016
Admission routes1
Has abstractyes

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