[2.2]Paracyclophane-based single molecular wire consisting of four π-electron systems
Bibliographic record
Abstract
A [2.2]paracyclophane-based through-space–conjugated tetramer comprising four partially stacked π-electron systems was designed and synthesized, with a large overlap integral between the photoluminescence spectrum of the terminal π-electron system of the through-space–conjugated trimer and the absorption band of the fourth π-electron system. Efficient unidirectional photoexcited energy transfer in the tetramer occurred by the Förster mechanism; the energy transfer efficiency and related rate constants were found to be >0.999 and >10 12 s –1 , respectively, and stepwise energy transfer was found to be dominant. The [2.2]paracyclophane-based tetramer acted as a single molecular wire for efficient unidirectional photoexcited energy transfer.
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How this classification was reachedexpand
Full frame distilled prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.001 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.000 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.001 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from itClassification
machine, unvalidatedMachine predicted; a candidate call from one teacher head, not a consensus.
How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".