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Record W2555596007 · doi:10.1021/acs.iecr.6b03746

Novel Fluidizable K-Doped HAc-Li<sub>4</sub>SiO<sub>4</sub> Sorbent for CO<sub>2</sub> Capture Preparation and Characterization

2016· article· en· W2555596007 on OpenAlexafffund
Sai Zhang, Muhammad B.I. Chowdhury, Qi Zhang, Hugo de Lasa

Bibliographic record

VenueIndustrial & Engineering Chemistry Research · 2016
Typearticle
Languageen
FieldEngineering
TopicChemical Looping and Thermochemical Processes
Canadian institutionsWestern University
FundersChina Scholarship CouncilNatural Sciences and Engineering Research Council of CanadaNational Natural Science Foundation of ChinaNatural Science Foundation of Shanghai
KeywordsSorbentSorptionCarbonationDesorptionMaterials scienceNuclear chemistryChemical engineeringDopingAdsorptionChemistryOrganic chemistryComposite material

Abstract

fetched live from OpenAlex

A novel fluidizable K-doped HAc-Li 4 SiO 4 sorbent using an incipient impregnation method was prepared in this work. The produced sorbent displayed an excellent CO 2 sorption capacity and stability under expected reaction conditions. Glacial acetic acid treatment was first used to modify the Li 4 SiO 4 sorbent microstructure. Following this step, an incipient impregnation method was applied to dope potassium onto the sorbent in order to further enhance the sorbent sorption capacity. This novel K-doped HAc-Li 4 SiO 4 sorbent was characterized using X-ray diffraction, N 2 adsorption–desorption, CO 2 temperature-programmed carbonation (CO 2 -TPC), and CO 2 temperature-programmed decarbonation (CO 2 -TPDC) analyses. The experimental results showed that the CO 2 sorption capacity of the K-doped HAc-Li 4 SiO 4 sorbent is approximately 100 cm 3 STP CO 2 /g sorbent. This was five times that of the Li 4 SiO 4 sorbent. Furthermore, the cyclic test of the K-doped HAc-Li 4 SiO 4 sorbent demonstrated it to be high and stable for CO 2 capture.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.001
Threshold uncertainty score0.003

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0010.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0010.000
Insufficient payload (model declined to judge)0.0010.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.041
GPT teacher head0.278
Teacher spread0.237 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations44
Published2016
Admission routes2
Has abstractyes

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