Rhodium dimers as structural hubs for multichromophore assemblies
Bibliographic record
Abstract
Our main building blocks for forming supra-molecular assemblies of chromophoric units are the rhodium amidinate dimers. They offer an excellent structural backbone for rigid polynuclear assemblies with their paddle wheel motif and strongly bonded ligands. We already showed that with a well designed amidinate ligand with a pyridyl group up to four metallic centers can be attached to the dimer.[1,2] Two main approaches were used to extend these assemblies: the first is through Suzuki coupling reactions which allows for an extended ligand and a control on the number of pyridyl present on the dimer; The second is through bisisocyanide ligands which are used to bridge the dimers though their axial site, thus forming 1D coordination polymer in the solid state. These different assemblies will be presented with their solid state structure, photophysical and electrochemical properties.
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How this classification was reachedexpand
Full frame distilled prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.000 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.000 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from itClassification
machine, unvalidatedMachine predicted; a candidate call from one teacher head, not a consensus.
How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".