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Record W2559169909 · doi:10.1107/s2053273314084654

Structure, bonding and dynamcs under extreme conditions

2014· article· en· W2559169909 on OpenAlexaff
John S. Tse

Bibliographic record

VenueActa Crystallographica Section A Foundations and Advances · 2014
Typearticle
Languageen
FieldChemistry
TopicChemical Thermodynamics and Molecular Structure
Canadian institutionsUniversity of Saskatchewan
Fundersnot available
KeywordsHigh pressureStructural changeMaterials scienceMolecular dynamicsStructural complexityChemical physicsNanotechnologyBiochemical engineeringComputer scienceChemistryComputational chemistryThermodynamicsPhysicsEngineeringArtificial intelligence

Abstract

fetched live from OpenAlex

Knowledge on the composition and structure of a material are essential to the understanding of the properties. Recent advances in structural prediction techniques from first-principles calculations have greatly enhanced the perspective on the large variety of new crystal types, particularly, under extreme conditions at high pressure and high temperature. The structural information helps to develop a new understanding on the change in chemical bonding in highly compressed solids. I will present the results and experience in the use of several structural prediction methods with examples drawn from recent studies on the outstanding problems in pressure-induced amorphization of SnI4, structural transformations, atomic dynamics and structural chemistry of simple elemental and molecular solids at high pressure and high temperature. Our results will highlight the successes, challenges and future development on the practical applications of these methods.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: none
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.961
Threshold uncertainty score0.629

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.008
GPT teacher head0.239
Teacher spread0.231 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations0
Published2014
Admission routes1
Has abstractyes

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