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Record W2561438374 · doi:10.1021/acs.jpcc.6b09615

Rate of Hydrogen Combustion in Supercritical Water

2016· article· en· W2561438374 on OpenAlexafffund
Dimitrios T. Kallikragas, Igor M. Svishchev, Kashif I. Choudhry

Bibliographic record

VenueThe Journal of Physical Chemistry C · 2016
Typearticle
Languageen
FieldEngineering
TopicSubcritical and Supercritical Water Processes
Canadian institutionsTrent University
FundersOffice of Energy Research and DevelopmentNatural Sciences and Engineering Research Council of CanadaAtomic Energy of Canada Limited
KeywordsSupercritical fluidHydrogenChemistrySupercritical water oxidationActivation energyCombustionChemical kineticsHydrogen fuelOxygenOxideInorganic chemistryKineticsReaction rateMetalReaction rate constantChemical engineeringCatalysisPhysical chemistryOrganic chemistry

Abstract

fetched live from OpenAlex

Hydrogen is a clean burning energy source and an essential oxygen scavenger used in corrosion control chemistry for nuclear power plants. Here, we report on the combustion rate of hydrogen in supercritical water. The reaction of hydrogen oxidation by oxygen is studied in a flow-through reactor operating under continuous steady state conditions in terms of surface oxidation. Hydrogen released in situ from the metal oxide reactor surface is accounted for in the overall reaction kinetics. Rate constants are presented for 500, 550, and 650 °C at 25 MPa. The activation energy for the homogeneous oxidation reaction is estimated to be 96.4 kJ mol –1 . This value is comparable with the activation energies obtained for other small fuel molecules.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.007
Threshold uncertainty score0.164

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.007
GPT teacher head0.208
Teacher spread0.201 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations10
Published2016
Admission routes2
Has abstractyes

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