Electrochemical Properties of Closo-2,3-dicarbaundecaborane in Dichloromethane at a Glassy Carbon Electrode using Potentiostatic, Galvanostatic and Digital Simulation Methods
Bibliographic record
Abstract
Electrochemical properties of closo-2,3-dicarbaundecaborane cluster have been investigated potentiostatically using cyclic voltammetry, convolutive voltammetry and galvanostatically via chronopotentiometry techniques combined with digital simulation method at a glassy carbon electrode in 0.1 M tetrabutylammonium perchlorate (TBAP) in solvent dichloromethane. The electroreduction of the carborane cluster exhibited two reduction peaks. The first peak was attributed to a two - electron reduction of carborane to form the dianion. Both the charge transfer processes were followed by fast chemical processes. The second peak represents the further reduction of the dianion by gain one electron to form the trianion followed by a fast chemical reaction. The chemical processes which follow the two - steps of the charge transfer may be due to fast isomerization or structural rearrangement The chemical and lectrochemical parameters of the investigated carborane were determined experimentally and verified theoretically via digital simulation method.
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How this classification was reachedexpand
Full frame machine prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.
Distilled classifier scores by category (both heads)
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.000 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.001 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from itClassification
machine, unvalidatedMachine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.
How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".