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Record W2576871529 · doi:10.1021/acs.jpclett.6b02861

Morphological Transformation of Surface Femtodroplets upon Dissolution

2017· article· en· W2576871529 on OpenAlexfundno aff
Shuhua Peng, Bat‐El Pinchasik, Hao Hao, Helmuth Möhwald, Xuehua Zhang

Bibliographic record

VenueThe Journal of Physical Chemistry Letters · 2017
Typearticle
Languageen
FieldEngineering
TopicInnovative Microfluidic and Catalytic Techniques Innovation
Canadian institutionsnot available
FundersRMIT UniversityAustralian Renewable Energy AgencyNorthumbria UniversityAustralian Research CouncilOntario Ministry of Natural Resources and Forestry
KeywordsDissolutionSurface energyMaterials scienceSurface (topology)Work (physics)Chemical physicsVolume (thermodynamics)Symmetry (geometry)Morphology (biology)Transformation (genetics)NanotechnologyMechanicsChemistryGeometryThermodynamicsPhysicsComposite materialMathematicsPhysical chemistry

Abstract

fetched live from OpenAlex

Constructing controllable liquid patterns with high resolution and accuracy is of great importance in droplet depositions for a range of applications. Simple surface chemical micropatterns have been popularly used to regulate the shape of liquid droplets and the final structure of deposited materials. In this work, we study the morphological evolution of a dissolving femtoliter droplet pinned on multiple microdomains. On the basis of minimization of interfacial energy, the numerical simulations predict various symmetric droplet profiles in equilibrium at different liquid volumes. However, our experimental results show both symmetric and asymmetric shapes of droplets due to contact line pinning and symmetry breaking during droplet dissolution. Upon slow volume reduction, the deposited microdroplet arrays on one single type of simple surface prepatterns spontaneously morphed into a series of complex regular 3D shapes. The findings in this work offer insights into design and prepararion of the rich and complex morphology of liquid patterns via simple surface premicropatterns.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.001
Threshold uncertainty score0.003

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0010.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.013
GPT teacher head0.244
Teacher spread0.231 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations20
Published2017
Admission routes1
Has abstractyes

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