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Record W2582616359

Heat Generation Measurements of Prismatic Lithium Ion Batteries

2013· dissertation· en· W2582616359 on OpenAlexfundno aff
Kaiwei Chen

Bibliographic record

VenueUWSpace (University of Waterloo) · 2013
Typedissertation
Languageen
FieldEngineering
TopicAdvancements in Battery Materials
Canadian institutionsnot available
FundersNatural Sciences and Engineering Research Council of Canada
KeywordsLithium (medication)IonMaterials scienceNuclear engineeringMechanical engineeringEngineering physicsEngineeringChemistryPsychology
DOInot available

Abstract

fetched live from OpenAlex

Electric and hybrid electric vehicles are gaining momentum as a sustainable alternative to conventional combustion based transportation. The operating temperature of the vehicle will vary significantly over the vehicle lifetime and this variance in operating temperature will strongly impact the performance, driving range, and durability of batteries used in the vehicles. 
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\nIn the first part of this thesis, an experimental facility is developed to accurately quantify the effects of battery operating temperature on discharge characteristics through precise control of the battery operating temperatures, utilizing a water-ethylene glycol solution in a constant temperature thermal bath. A prismatic 20Ah LiFEPO4 battery from A123 is tested using the developed method, and temperature measurements on the battery throughout discharge show a maximum variation of 0.3°C temporally and 0.4°C spatially at a 3C discharge rate, in contrast to 13.1°C temperature change temporally and 4.3°C spatially when using the conventional air convection temperature control method under the same test conditions. A comparison of battery discharge curves using the two methods show that the reduction in spatial and temporal temperature change in the battery has a large effect on the battery discharge characteristics. The developed method of battery temperature control yields more accurate battery discharge characterization due to both the elimination of state-of-charge drift caused by spatial variations in battery temperature, and inaccurate discharge characteristics due to battery heat up at various discharge and ambient conditions. Battery discharge characterization performed using the developed method of temperature control exhibits a reduction in battery capacity of 95% when the operating temperature is decreased from 20°C to -10°C at 3C discharge rate. A reduction of 35% in battery capacity is observed when for the same temperature decrease at a 0.2C discharge rate. The observed effect of operating temperature on the capacity of the tested battery highlights the importance of an effective thermal management system, the design of which requires accurate knowledge of the heat generation characteristics of the battery under various discharge rates and operating temperatures. 
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\nIn the second part of this thesis, a calorimeter capable of measuring the heat generation rates of a prismatic battery is developed and verified by using a controllable electric heater. The heat generation rate of a prismatic A123 LiFePO4 battery is measured for discharge rates ranging from 0.25C to 3C and operating temperature ranging from -10°C to 40°C. Results show that the heat generation rates of Lithium ion batteries are greatly affected by both battery operating temperature and discharge rate. At low rates of discharge the heat generation is not significant, even becoming endothermic at the battery operating temperatures of 30°C and 40°C. Heat of mixing is observed to be a non-negligible component of total heat generation at discharge rates as low as 0.25C for all tested battery operating temperatures. A double plateau in battery discharge curve is observed for operating temperatures of 30°C and 40°C. The developed experimental facility can be used for the measurement of heat generation for any prismatic battery, regardless of chemistries. The characterization of heat generated by the battery under various discharge rates and operating temperatures can be used to verify the accuracy of battery heat generation models currently used, and for the design of an effective thermal management system for electric and hybrid electric vehicles in the automotive industry.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesMeta-epidemiology (narrow)
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.308
Threshold uncertainty score1.000

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0010.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.021
GPT teacher head0.208
Teacher spread0.187 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations10
Published2013
Admission routes1
Has abstractyes

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