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Record W2587710698 · doi:10.1149/2.021706jss

LiF Doping of C<sub>60</sub>Studied with X-ray Photoemission Shake-Up Analysis

2017· article· en· W2587710698 on OpenAlexafffund
Ayse Turak, Marek Z. Zgierski, M. W. C. Dharma‐wardana

Bibliographic record

VenueECS Journal of Solid State Science and Technology · 2017
Typearticle
Languageen
FieldChemistry
TopicFullerene Chemistry and Applications
Canadian institutionsNational Research Council CanadaMcMaster University
FundersUniversity of Toronto
KeywordsMaterials scienceFullereneX-ray photoelectron spectroscopyDissociation (chemistry)DopingPhotoemission spectroscopyAtomic physicsCovalent bondChemical physicsAnalytical Chemistry (journal)Physical chemistryNuclear magnetic resonanceChemistryOptoelectronicsOrganic chemistry

Abstract

fetched live from OpenAlex

We report our investigation of the chemical doping mechanism induced by LiF interaction with fullerene thin films. High resolution X-ray photoelectron spectroscopy of the C 1s shake-up satellites and F 1s main core level, supported by density functional calculations, suggest the formation of a charge transfer complex between covalent LiF monomers and dimers and C 60 . This interaction was observed in both LiF/C 60 and C 60 /LiF depositions, suggesting that some charge transfer complexation can occur in these systems even without dissociation.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.002
Threshold uncertainty score0.008

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0010.000
Scholarly communication0.0010.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0020.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.013
GPT teacher head0.276
Teacher spread0.264 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations10
Published2017
Admission routes2
Has abstractyes

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Same venueECS Journal of Solid State Science and TechnologySame topicFullerene Chemistry and ApplicationsFrench-language works237,207