Odyssey of Multivalent Cathode Materials: Open Questions and Future Challenges
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No Canadian affiliation. An affiliation-only frame — the usual design — would never have seen this work. It is one of the works that make the case for inverting the frame.
Abstract
The rapidly expanding field of nonaqueous multivalent intercalation batteries offers a promising way to overcome safety, cost, and energy density limitations of state-of-the-art Li-ion battery technology. We present a critical and rigorous analysis of the increasing volume of multivalent battery research, focusing on a wide range of intercalation cathode materials and the mechanisms of multivalent ion insertion and migration within those frameworks. The present analysis covers a wide variety of material chemistries, including chalcogenides, oxides, and polyanions, highlighting merits and challenges of each class of materials as multivalent cathodes. The review underscores the overlap of experiments and theory, ranging from charting the design metrics useful for developing the next generation of MV-cathodes to targeted in-depth studies rationalizing complex experimental results. On the basis of our critical review of the literature, we provide suggestions for future multivalent cathode studies, including a strong emphasis on the unambiguous characterization of the intercalation mechanisms.
Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.
The record
- Venue
- Chemical Reviews
- Topic
- Advancements in Battery Materials
- Field
- Engineering
- Canadian institutions
- —
- Funders
- Lawrence Berkeley National LaboratoryBasic Energy SciencesOffice of ScienceUniversity of Illinois at Urbana-ChampaignBar-Ilan UniversityUniversity of Illinois at ChicagoUniversity of WaterlooU.S. Department of Energy
- Keywords
- CathodeIntercalation (chemistry)Battery (electricity)ChemistryNanotechnologyEngineering physicsInorganic chemistryMaterials sciencePhysical chemistryPhysics
- Has abstract in OpenAlex
- yes