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Record W2592156092 · doi:10.1107/s2056989017003498

Synthesis and crystal structure of bis(μ-2-methylbenzenethiolato-κ<sup>2</sup><i>S</i>:<i>S</i>)bis[methyl(2-methylbenzenethiolato-κ<i>S</i>)indium(III)]

2017· article· en· W2592156092 on OpenAlex
Glen G. Briand, A. Decken, Courtney M. Dickie, Gregory A. MacNeil

Why this work is in the frame

A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.

affAt least one author lists a Canadian institution in the pinned OpenAlex snapshot.
fundA Canadian funder is recorded on the work.

Bibliographic record

VenueActa Crystallographica Section E Crystallographic Communications · 2017
Typearticle
Languageen
FieldChemistry
TopicOrganometallic Compounds Synthesis and Characterization
Canadian institutionsUniversity of New BrunswickMount Allison University
FundersNatural Sciences and Engineering Research Council of CanadaMount Allison UniversityNew Brunswick Innovation FoundationCanada Foundation for Innovation
KeywordsChemistryCrystal structureCrystallographyIntermolecular forceIndiumRing (chemistry)StereochemistryTolueneBipyramidTrigonal bipyramidal molecular geometryMoleculeOrganic chemistry

Abstract

fetched live from OpenAlex

The dinuclear title compound, [In 2 (CH 3 ) 2 (C 7 H 7 S) 4 ] or [Me(2-MeC 6 H 4 S)In-μ-(2-MeC 6 H 4 S) 2 InMe(2-MeC 6 H 4 S)], was prepared from the 1:2 reaction of Me 3 In and 2-MeC 6 H 4 SH in toluene. Its crystal structure exhibits a four-membered In 2 S 2 ring core via bridging (2-MeC 6 H 4 S) groups. The dimeric units are further associated into a one-dimensional polymeric structure extending parallel to the a axis via intermolecular In...S contacts. The In atoms are then in distorted trigonal–bipyramidal CS 4 bonding environments.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.001
metaresearch head score (Gemma)0.001
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesMeta-epidemiology (narrow), Science and technology studies, Research integrity, Insufficient payload (model declined to judge)
Consensus categoriesScience and technology studies
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: none
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.885
Threshold uncertainty score1.000

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0010.001
Meta-epidemiology (narrow)0.0010.001
Meta-epidemiology (broad)0.0020.001
Bibliometrics0.0020.001
Science and technology studies0.0040.003
Scholarly communication0.0010.002
Open science0.0040.002
Research integrity0.0010.002
Insufficient payload (model declined to judge)0.0010.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.015
GPT teacher head0.241
Teacher spread0.225 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it