Influence of the Functionalization Degree of Multiwalled Carbon Nanotubes on the Immobilization of Polyoxometalates and Its Effect on their Electrochemical Behavior
Bibliographic record
Abstract
Hybrid materials based on the anchoring polyoxometalate particles POM on several multiwalled carbon nanotubes (NTs) matrices with different oxidation degree are characterized and electrochemically studied, in order to correlate the dispersion degree of POM particles on these matrices with their electrochemical behavior. These hybrids synthesized with soluble PMo12 particles resulted in truly homogenous hybrids and are analyzed by XRD, SEM, EDS, TEM, and N2 adsorption isotherms in order to confirm the presence of their components and their dispersion properties. Higher dispersion of PMo12 nanoparticles is the main factor contributing to an improved electrochemical behavior in these types of hybrid materials, making hybrid NT-S-PMo12 with this property the one resulting in the best electrochemical performance where the redox contribution of PMo12 particles are clearly observed as well as the improved double layer contribution of its nanotube matrix (NT-S, highly oxidized).
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How this classification was reachedexpand
Full frame distilled prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.001 | 0.001 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.001 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.000 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.000 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from itClassification
machine, unvalidatedMachine predicted; a candidate call from one teacher head, not a consensus.
How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".